Why would
anyone want to debunk a theory? Simply because following a false theory to an
extension of practicality may very well lead to disaster.
Does global
warming exist? I don't know, but I will guess that it probably does. There is a
lot of conflicting evidence on temperature taking at various locations,
discussions of ice thickness, etc., but the preponderance of evidence seems to
indicate there is some slight global warming in the recent past. Why?
My
purpose here is not to discuss the pros and cons of global warming but rather to
concentrate on the theory that any global warming is resulting from the man's
activity. I am particularly interested in increased emission of carbon dioxide
through the burning of fossil fuels, and now an increase in atmospheric methane
concentration, through leakage natural gas wells.
Global Warming Theory
says that the primary increase in global warming is caused by this increase in
the atmospheric concentration of these two gases. To support the theory, the
term Greenhouse Gas has been developed and needs to be understood.
The
National Climatic Data Center of the National Oceanic and Atmospheric
Administration says in its website (http://www.ncdc.noaa.gov/oa/climate/gases.html) that greenhouse gases allow direct sunlight to reach the Earth's
surface unimpeded. As the short-wave energy heats the surface, heat is
reradiated to the atmosphere. Greenhouse gases absorb this energy (heat),
thereby allowing less heat to escape back to space, and 'trapping' it in the
lower atmosphere. Another way to say this is that sunlight heats up your car
and the heat cannot escape to interstellar space, because greenhouse gases block
the escape.
I have no quarrel with this. Atmospheric gases do impede the
escape of heat from a terrestrial body. For example, the moon has no gases and
there are great extremes of temperature. Conversely, the greenhouse gases of the
Earth equalize temperatures, so that the difference between day and night
temperatures are not so great as to make the place unlivable.
What are
these greenhouse gases? Since we know that Earth's atmosphere is 79% nitrogen
and 21% oxygen, with trace amounts of many other gases, it's a fair assumption
that the greenhouse gas of Earth is composed primarily of nitrogen and
oxygen.
However, the Global Warming Theory enthusiasts are not satisfied
with the obvious. For whatever reasons they may have, they desire to complicate
the issue by attributing a special effect of higher global warming to the
presence of the trace gases, particularly carbon dioxide and methane.
The
special effects are further defined by a mathematical term for Global Warming
Potential. The equation is attached. If you look at it, don't be intimidated.
Notice that there is a term for an investigated gas in the numerator and an
equivalent term for carbon dioxide in the denominator. All this says is that we
calculate the Global Warming Potential of any gas in relation to carbon dioxide.
The assumption is that carbon dioxide is bad. It also says nothing about Global
Warming EFFECTS. In other words it says nothing about how much nitrogen or
oxygen contribute to the greenhouse effect of stabilizing temperatures, nor does
it consider carbon dioxide and methane for that same activity.
A little
common sense tells you that in order for anything to have an effect on something
else, it has to be present. If it's not there, it cannot have an effect. A
reasonable extension of this thought that the more a substance is present, the
greater will be its effect. Example, a glass of whiskey at 70% alcohol contains
more alcohol than a glass of wine at 20% alcohol. The glass of whiskey will go
farther toward inebriation than the glass of wine.
Therefore, it stands
to reason that because of the high concentrations of nitrogen and oxygen in the
atmosphere, those gases will likely have a much greater effect on temperature
equalization of the earth than will any trace gases. The only way this could not
be true is if the trace gases have a very special attribute compared to nitrogen
and oxygen. We are already seeing that the Global Warming Potential
Equation does not address this possibility.
Advocates of global warming increase caused by
man-generated increases in carbon dioxide and methane to the atmosphere have
developed another equation. The equation for Radiative Forcing Capacity (RF) is
also attached. Again, do not be intimidated by the equation. The only term of
significance that it contains is the infrared absorption of the gas being
considered. That is, how much heat can a gas hold? Well, good! At least we have
something that starts to concern the practical aspects of the atmosphere. We can
calculate the RF of nitrogen, oxygen or any gas, but no one seems to have done
that.
But we also must return to common sense. While one gas may be able
to hold more heat than another gas, it is obvious that the amount of gas present
is an important factor. In other words, we must consider gas concentrations in
the atmosphere. Let's compare the heats that could be held in the atmosphere by
nitrogen and carbon dioxide. Let's take million parts of atmospheric gas. Of
that total there are 790,000 parts of nitrogen. Making up a number, let's also
say that each part of nitrogen can hold 1 calorie of heat. The content then for
the nitrogen is 790,000 calories. Doing the same thing with carbon dioxide,
there are 350 parts in the million parts of atmospheric gas. Let's also say that
a part of carbon dioxide can hold twice as much heat as nitrogen. That would be
2 calories per part. With the 350 parts of carbon dioxide at 2 calories per
part, the total heat content of the carbon dioxide would be 700 calories. Notice
that the content of the carbon dioxide is only 0.08% of that held by the
nitrogen. Not much effect. Let's also say that perhaps the carbon dioxide can
hold 100 times more heat than the nitrogen. It's heat content would then be 4%.
Still only borderline with respect to effectiveness, and we haven't even yet
considered that the presence of oxygen would also bring that value down. We then
also have to ask ourselves whether it is even reasonable that one part of carbon
dioxide could be 100 times more effective in holding heat than one part of
nitrogen. But these are calculations that actually could be made using the RF
equation.
Some have said there could be huge differences in the RF's of
various gases. They have likened the action of heat without light, which is a
reasonable comparison. When light strikes the surface, it can be transmitted,
absorbed, or reflected. Usually all three actions occur, but in different
amounts depending upon the object which the light strikes. For example, when
light strikes glass, a large portion of it is transmitted. If light strikes a
black object, a large portion of the light is absorbed. And if light strikes a
reflective surface, such as a shiny metal, a large portion will be reflected.
But notice that in order to have these large differences, we had to materially
change the nature of the object being struck by light. In the atmosphere, we
don't have these large differences. All components are gases. True. Some have
two items per molecule, such as nitrogen and oxygen. Some have three atoms per
molecule, such as carbon dioxide. And, some have four atoms per molecule, such
as methane.
However, we do have some real data on heat transmission
through various gases, which is exactly our case in greenhouse gas
considerations. Thermal conductivity is the rate at which heat can pass through
a substance. The Gas Encyclopedia by Air Liquide (http://encyclopedia.airliquide.com/encyclopedia.asp)
gives thermal conductivity for many pure gases. Thermal conductivities for both
nitrogen and oxygen are about 24. For carbon dioxide, it is 14 and for methane
32. Since the higher the thermal conductivity, the less heat is being absorbed
by a gas, it is apparent that carbon dioxide absorbs more heat than nitrogen and
oxygen. Conversely, methane absorbs less heat. Another important factor is the
ratio of the numbers. If we take carbon dioxide, it is 1.7 times more effective
than nitrogen in absorbing heat. Notice that we said earlier that if carbon
dioxide would be twice as effective as nitrogen in heat holding, the mere fact
that there's so little of it would make a heat absorption difference in the
atmosphere of only 0.08%.
For strong believers that any observed global warming is
caused by an increase in atmospheric carbon dioxide concentration through
burning fossil fuels, I hope that the above presentation has shed a little doubt
on that presumption. At least, I feel that considering heat absorption of major
atmospheric gases, rather than considering only trace gases, is a realistic
approach to determining total heat effects related to greenhouse gases and
global warming.
Reference: http://en.wikipedia.org/wiki/Global-warming_potential
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